Ti scheme 1
Notes
Developed by Trappitsch at al. at Lawrence Livermore National Laboratory using the LION instrument. The useful yield for the overall scheme (all transitions) is estimated to be 18%.
Scheme
Ionization Potential: 55072.500 cm⁻¹ (NIST ASD, 2024)
Lasers used: Ti:Sa
Scheme table
| Step | λ (nm) | From (cm⁻¹) | Term | To (cm⁻¹) | Term |
|---|---|---|---|---|---|
| 1 | 465.777 | 0.00 | 3F2 | 21469.50 | 3G3 |
| 1 | 469.498 | 170.15 | 3F3 | 21469.50 | 3G3 |
| 1 | 474.324 | 386.88 | 3F4 | 21469.50 | 3G3 |
| 2 | 416.158 | 21469.50 | 3G3 | 45498.85 | 3G4 |
| 3 | 881.399 | 45498.85 | 3G4 | 56844.45 |
Scheme drawing

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Saturation curves
1st transition (465.777 nm)
First transition from ground state at 0 cm¯¹.

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1st transition (469.498 nm)
First transiton from ground state at 170.15 cm¯¹.1

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1st transition (474.324 nm)
First transition from low-lying state at 318.88 cm¯¹. This transition is not saturated.

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2nd transition (416.158 nm)

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Ionizing transition (881.399 nm)

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References
Submitted by
Reto Trappitsch